Lewis acid adducts of [PCl2N]3 |
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Authors: | Heston Amy J Panzner Matthew J Youngs Wiley J Tessier Claire A |
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Affiliation: | Department of Chemistry, University of Akron, 190 East Buchtel Commons, Akron, OH 44325-3601, USA. |
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Abstract: | Reaction of aluminum trichloride or gallium trichloride with the extremely weak base hexachlorotriphosphazene gives adducts in which the group 13 element is bound to a phosphazene nitrogen atom. In solution, the adducts exhibit fluxional behavior. The phosphazene ring of the adducts is distorted into a slight chair conformation. |
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