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Lewis acid adducts of [PCl2N]3
Authors:Heston Amy J  Panzner Matthew J  Youngs Wiley J  Tessier Claire A
Affiliation:Department of Chemistry, University of Akron, 190 East Buchtel Commons, Akron, OH 44325-3601, USA.
Abstract:Reaction of aluminum trichloride or gallium trichloride with the extremely weak base hexachlorotriphosphazene gives adducts in which the group 13 element is bound to a phosphazene nitrogen atom. In solution, the adducts exhibit fluxional behavior. The phosphazene ring of the adducts is distorted into a slight chair conformation.
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