The use of selenophenyl galactopyranosides for the synthesis of α and β-(1→4)-C-disaccharides |
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Authors: | Astrid Mallet Jean-Maurice Mallet Pierre Sinay |
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Affiliation: | Astrid Mallet, Jean-Maurice Mallet,Pierre Sinay, * |
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Abstract: | Methyl α-C-lactoside {β-D-Gilp-C-(1→4)-α-D-Glcp-OMe} and its α anomer were expeditiously synthesized by radical coupling of various selenophenyl galactopyranosides onto methyl 2,3-di-O-benzyl-4-deoxy-4-C-methylene-α-D-xylo-hexopyranoside, which aretemporarily connected through a silaketal tether. |
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