Azidokomplexe in nicht-wäßrigen Lösungen, 1. Mitt.: Co(II), Ni(II) und Cu(II) in Acetonitril,Trimethylphosphat und Dimethylsulfoxid |
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| Authors: | V Gutmann O Leitmann |
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| Institution: | 1. Institut für Anorganische und Allgemeine Chemie der Technischen Hochschule Wien, Wien, ?sterreich
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| Abstract: | The formation of azido complexes is investigated inDMSO, TMP andAN by spectrophotometric, potentiometric (Tl/TlN3-electrode) and conductometric methods. The following coordination forms were established: CoN3]+ (octahedral, inTMP), Co(N3)2] (tetrahedral, inTMP, AN andDMSO), Co(N3)4]2? (tetrahedral, inTMP, AN andDMSO); Ni(N3)2 and Ni(N3)4]2? (either, inTMP, AN andDMSO), CuN3]+ and Cu(N3)2] (both inTMP, AN andDMSO), Cu(N3)3]? (tetrahedral, inTMP andAN) and Cu(N3)4]2? (tetrahedral, inTMP, AN andDMSO). |
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