Über das polarographische Verhalten der syn- und anti-Isomeren der Ketoxime

Both the syn(α)- and the anti(β)-isomers of 4-chlorobenzophenoneoxime show two polarographic steps; the first is limited by diffusion kinetics, but the second solely by diffusion. As with aldoximes, the limiting current ratioi ₁/i ₂ decreases with increasing concentration of the organic solvent; at equal concentration one can write

$$left( {frac{{i_1 }}{{i_2 }}} right)_alpha< left( {frac{{i_1 }}{{i_2 }}} right)_beta $$