Some less usual properties of tetracyano complexes |
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Authors: | Anna Sopková Michal Šingliar Ján Skoršepa Juraj Matanin Eva Terpáková |
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Affiliation: | (1) Department of Inorganic Chemistry, Faculty of Sciences, University P. J. afárik, 041 57 Koice, Czechoslovakia;(2) Present address: Institute of Petrochemistry, 972 71 Nováky, Czechoslovakia |
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Abstract: | The structure and reactivity of one unique molecule may be understood only in relation to its molecular surroundings. The non-stoichiometric forms of the tetracyano complexes M(B)mM (CN)4·nG (B=nitrogen or oxygen containing base; G=aromatic compound or H2O,m0,n>0) are understood in this respect. Their stoichiometric or non-stoichiometric forms, with voids either completely or more often partially occupied, are responsible for their observed sorptive and resorptive abilities. The effects of the surroundings are correlated with the results of thermal analysis, magnetic measurements and their sorptive abilities.Dedicated to Professor H. M. Powell. |
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Keywords: | clathrate molecular system metal tetracyano complex hydrate clathrate sorption magnetic susceptibility |
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