| Syntheses and Crystal Structures of Benzyltin（Ⅳ） Derivatives of 2-Mercaptobenzothiazole |
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| 引用本文： | 张如芬,邱林林,李凤,马春林. Syntheses and Crystal Structures of Benzyltin（Ⅳ） Derivatives of 2-Mercaptobenzothiazole[J]. 中国化学, 2004, 22(7): 768-773. DOI: 10.1002/cjoc.20040220731 |
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| 作者姓名： | 张如芬 邱林林 李凤 马春林 |
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| 作者单位： | Department of Chemistry，Liaocheng University，Liaocheng，Shandong 252059，China，Department of Chemistry，Taishan University，Taian，Shandong 271021，China，Department of Chemistry，Liaocheng University，Liaocheng，Shandong 252059，China，Department of Chemistry，Liaocheng University，Liaocheng，Shandong 252059，China Department of Chemistry，Taishan University，Taian，Shandong 271021，China |
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| 基金项目： | Project supported by the Natural Science Foundation of Shangdong Province. |
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| 摘 要： | Introduction Metal thiolato complexes have been extensively investigated because of their ability to adopt various nuclearities and their relevance in biological science, since they form the inorganic part of the biologically active centers of some metalloproteins and enzymes.1-3 Recently, attention has been paid to the coordination chemistry of heterocyclic thiol/thione donors, which can give potential access to new compounds with unusual structures and reactivities,4 such as 2-mercaptobenzo-…
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| 关 键 词： | 合成 晶体结构 苄基锡衍生物 2-巯苯噻唑 二齿配位基 氮原子 硫原子 |
Syntheses and crystal structures of benzyltin(IV) derivatives of 2‐mercaptobenzothiazole |
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| ZHANG,Ru-Fena QIU,Lin-Linb LI,Fenga MA,Chun-Lin,a,b a. Syntheses and crystal structures of benzyltin(IV) derivatives of 2‐mercaptobenzothiazole[J]. Chinese Journal of Chemistry, 2004, 22(7): 768-773. DOI: 10.1002/cjoc.20040220731 |
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| Authors: | ZHANG Ru-Fena QIU Lin-Linb LI Fenga MA Chun-Lin a b a |
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| Affiliation: | ZHANG,Ru-Fena QIU,Lin-Linb LI,Fenga MA,Chun-Lin*,a,b a Department of Chemistry,Liaocheng University,Liaocheng,Shandong 252059,China b Department of Chemistry,Taishan University,Taian,Shandong 271021,China |
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| Abstract: | The complexes (PhCH2)2Sn(MBT)2 (2) and (PhCH2)3Sn(MBT) (3) (HMBT: 2-mercaptobenzothiazole) have been synthesized and characterized by elemental analyses, and IR, 1H, 13C, 119Sn NMR spectrometries and X-ray diffraction. Studies on the crystal structures of 2 and 3 show that HMBT acts as bidentate ligand through chelation of N and S atoms. Complex 2 contains a six-coordinate tin atom with the axial angle C(15)-Sn(1)-C(22) 129.6(2). And the tin environment of complex 3 is a distorted cis-trigonal bipyramid with C(8)-Sn(1)-N(1) 158.80. |
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| Keywords: | crystal structure benzyltin(IV) derivative 2-mercaptobenzothiazole |
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