Liquid phase hydrogen transfer to cyclopentanone over MgO-I2 and MgO-RI catalysts |
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| Authors: | Marek Gli&# ski Urszula Ulkowska |
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| Affiliation: | (1) Faculty of Chemistry, Warsaw University of Technology (Politechnika), Noakowskiego 3, 00-664 Warsaw, Poland |
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| Abstract: | Instead of cyclopentanol, 2-cyclopentylidene-cyclopentanone is the main product of liquid phase hydrogen transfer from secondary alcohols to cyclopentanone in the presence of pure MgO [1]. In the present work it has been shown that a significant increase in the selectivity towards cyclopentanol has been observed for MgO treated with I2 or alkyl iodides. |
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| Keywords: | Hydrogen transfer cyclopentanone magnesium oxide aldol condensation |
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