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Early stages of ZnS nanoparticle growth studied by in-situ stopped-flow UV absorption spectroscopy.
Authors:Michael Tiemann  Ozlem Weiss  Juha Hartikainen  Frank Marlow  Mika Lindén
Institution:Institutionen f?r Fysikalisk Kemi, Abo Akademi, Porthansgatan 3-5, 20500 Abo, Finland.
Abstract:The early stages of ZnS nanoparticle growth from supersaturated solution are investigated in situ by stopped-flow UV absorption spectroscopy with a time resolution of 1.28 ms. A model for data analysis is suggested which makes it possible to study both the average particle radius and the concentration. The average radii lie in the sub-nanometer range. During the first 40 ms, growth is predominantly governed by ripening.
Keywords:absorption  crystal growth  nanostructures  quantum dots  UV/Vis spectroscopy
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