Phenanthro[4,5‐fgh]quinoxaline‐Fused Subphthalocyanines: Synthesis,Structure, and Spectroscopic Characterization |
| |
| Authors: | Houhe Pan Wenbo Liu Chiming Wang Kang Wang Prof. Dr. Jianzhuang Jiang |
| |
| Affiliation: | Beijing Key Laboratory for Science and Application of Functional, Molecular and Crystalline Materials, Department of Chemistry, University of Science and Technology Beijing, Beijing, P. R. China |
| |
| Abstract: | A series of four phenanthro[4,5‐fgh]quinoxaline‐fused subphthalocyanine derivatives 0 – 3 containing zero, one, two, and three phenanthro[4,5‐fgh]quinoxaline moieties, respectively, were isolated from the mixed cyclotrimerization reaction of 2,9‐di‐tert‐butylphenanthro[4,5‐fgh]quinoxaline‐5,6‐dicarbonitrile with 4,5‐bis(2,6‐diisopropylphenoxy)phthalonitrile and characterized by a series of spectroscopic methods including MALDI‐TOF mass, 1H NMR, electronic absorption, magnetic circular dichroism (MCD), and fluorescence spectroscopy. The molecular structures for the compounds 0 and 2 were clearly revealed on the basis of single‐crystal X‐ray diffraction analysis. Their electrochemical properties were also studied by cyclic voltammetry. In particular, theoretical calculations in combination with the electronic absorption and electrochemical analyses revealed the significant influence of the fused‐phenanthro[4,5‐fgh]quinoxaline units on the electronic structures. |
| |
| Keywords: | electrochemistry single-crystal structures subphthalocyanine analogues synthesis |
|
|
