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catena‐Poly[bis­[(1,10‐phenanthro­line)nickel(II)]‐μ‐3,6‐dicarboxy­cyclo­hexane‐1,2,4,5‐tetra­carboxyl­ato]
Authors:Zhi‐Feng Li  Hong‐Zhen Xie  Yue‐Qing Zheng
Abstract:In the title compound, Ni2(C12H8O12)(C12H8N2)2]n, the 3,6‐dicarboxy­cyclo­hexane‐1,2,4,5‐tetra­carboxyl­ate (H2chhc4−) anion has crystallographically imposed C2 symmetry and bridges the six‐coordinate Ni atoms to generate polymeric Ni2(H2chhc)2/2(C12H8N2)2] chains extending in the 010] direction. The coordination polymer chains are linked into a three‐dimensional framework by O—H⋯O and C—H⋯O hydrogen bonds.
Keywords:
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