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Hydrogen bonding in meso‐4,5‐diphenyl‐3,6‐diaza­octane‐1,8‐diol: the formation of one‐dimensional linear chains of edge‐fused rings
Authors:Muharrem Dinç  er,Namı  k Ö  zdemir,Sinan Saydam,Ö  zer Bekaroğ  lu,Orhan Bü    kgü  ngö  r
Abstract:The molecule of the title compound, C18H24N2O2, resides on a crystallographic inversion centre. The mol­ecule adopts a transoid conformation with respect to the central C—C single bond and is in the meso form. A polarimetric study of the compound did not show any optical activity, indicating that the compound is a racemic mixture entirely consistent with the centrosymmetric space group. In the mol­ecule, there is one intra­molecular N—H⋯O inter­action, resulting in the formation of a five‐membered ring. In the crystal structure, inter­molecular O—H⋯N and C—H⋯O inter­actions are also observed. These inter­actions form an R22(9) ring and one‐dimensional linear chains of edge‐fused rings running parallel to the [010] direction, which stabilize the crystal packing.
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