Poly[[aquacopper(II)]‐μ‐adamantane‐1,3‐diacetato] |
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Authors: | Denise J. Xu Long Pan Thomas J. Emge Xiao‐Ying Huang Jing Li |
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Abstract: | In the title compound, [Cu(C14H18O4)(H2O)]n, each CuII atom bonds to four O atoms of four adamantanediacetate (ada) ligands in equatorial positions and an O atom from a water molecule in the apical position. Two adjacent CuII atoms form a paddle‐wheel unit with four ada ligands. The distance between the two Cu atoms is 2.5977 (3) Å. A crystallographic inversion center is located at the center of the Cu–Cu core. Each Cu2(ada)4 paddle‐wheel further bonds to four adjacent identical paddle‐wheel units, generating a two‐dimensional layered structure of Cu(ada)(H2O) with a 44 topology. |
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