catena‐Poly[[[triaquasulfatocobalt(II)]‐μ‐4,4′‐bipyridine] ethane‐1,2‐diol solvate] |
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Authors: | Wen‐Jie Lu Yi‐Min Zhu Kai‐Long Zhong |
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Abstract: | In the title compound, {Co(SO4)(C10H8N2)(H2O)3]·C2H6O2}n, each CoII center is octahedrally coordinated by two N atoms from two bridging 4,4′‐bipyridine (bipy) ligands and four O atoms, one from a monodentate sulfate ligand and three from aqua ligands. The bipy ligands occupy special positions of site symmetry and bridge adjacent cobalt(II) centers to form one‐dimensional linear coordination chains. Adjacent chains are arranged in a cross‐like fashion around the mid‐point of the bipy ligands, resulting in a three‐dimensional supramolecular array. |
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