{2,5‐Bis[3‐(tert‐butylaminoxyl)phenyl]‐1,1‐dimethyl‐3,4‐diphenylsilole‐κO}bis(1,1,1,5,5,5‐hexafluoropentane‐2,4‐dionato)manganese(II) |
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Authors: | Nans Roques Philippe Gerbier Inhar Imaz Philippe Guionneau Jean‐Pascal Sutter |
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Abstract: | In the structure of the first bis‐adduct of 2,5‐bis[3‐(tert‐butylaminoxyl)phenyl]‐1,1‐dimethyl‐3,4‐diphenylsilole with bis(hexafluoroacetylacetonato)manganese(II), [Mn(C5HF6O2)2(C38H42N2O2Si)2], the Mn atom lies on a crystallographic inversion centre and is bound to two chelating hexafluoroacetylacetonate ligands and two monodentate nitroxide groups in a distorted octahedral configuration. The silole ligands present a propeller‐like arrangement of the benzene rings around the Si‐containing five‐membered ring. The dihedral angles between the complexed nitroxides and the benzene rings to which they are bound are smaller than those found in the free ligand. |
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