[Bis(trimethylsilyl)amido‐κN]{tert‐butyl[(E)‐2‐(tert‐butylimino)ethyl]amido‐κ2N,N′}tin(II), a key intermediate in the synthesis of 1,3‐di‐tert‐butyl‐2,3‐dihydro‐1H‐1,3,2‐diazastannole |
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Authors: | Ilia A Guzei Vitaliy I Timokhin Robert West |
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Abstract: | The title compound, Sn(C10H21N2)(C6H18NSi2)], contains the SnII centre in a trigonal–pyramidal geometry. The basal plane is formed by three N atoms and the fourth apical position is occupied by a stereoactive lone pair. The Sn atom is displaced from the plane of the three N atoms by 1.1968 (12) Å. The Sn—N bonds are highly polarized toward the N atoms, as confirmed by natural bonding orbital analysis. |
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