Abstract: | The title complex, μ‐octane‐1,8‐dioato‐bisbis(3‐aminopyridine)chloro(methanol)cobalt(II)], Co2(C8H12O4)Cl2(C5H6N2)4(CH4O)2], is located on a crystallographic centre of inversion. The coordination around each of the Co centres is distorted octahedral, involving two N, three O and one Cl atom. Discrete dimers are connected in a three‐dimensional arrangement through N—H?O, N—H?Cl and O—H?O hydrogen‐bond interactions. |