A zigzag chain structure in catena‐poly[[[tetra‐μ‐acetamidato‐κ4N:O;κ4O:N‐dirhodium(II,III)]‐μ‐chloro] methanol solvate] |
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Authors: | Masahiro Ebihara Yasuhiro Fuma |
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Abstract: | In {Rh2(C2H4NO)4Cl]·CH3OH}n, the cationic dirhodium complex and bridging chloro ligands form a one‐dimensional zigzag chain, Rh2(acam)4(μ‐Cl)] (Hacam is acetamide). There is a large difference between the two Rh—Cl distances 2.6076 (14) and 2.5027 (14) Å]. Neighboring chains are connected by two N—H⋯O hydrogen bonds per link between the amidate ligands. |
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