A zigzag chain structure in catena‐poly[[[tetra‐μ‐acetamidato‐κ4N:O;κ4O:N‐dirhodium(II,III)]‐μ‐chloro] methanol solvate]

In {Rh₂(C₂H₄NO)₄Cl]·CH₃OH}_n, the cationic dirhodium complex and bridging chloro ligands form a one‐dimensional zigzag chain, Rh₂(acam)₄(μ‐Cl)] (Hacam is acetamide). There is a large difference between the two Rh—Cl distances 2.6076 (14) and 2.5027 (14) Å]. Neighboring chains are connected by two N—H⋯O hydrogen bonds per link between the amidate ligands.