首页 | 本学科首页   官方微博 | 高级检索  
     检索      


A zigzag chain structure in catena‐poly[[[tetra‐μ‐acetamidato‐κ4N:O;κ4O:N‐dirhodium(II,III)]‐μ‐chloro] methanol solvate]
Authors:Masahiro Ebihara  Yasuhiro Fuma
Abstract:In {Rh2(C2H4NO)4Cl]·CH3OH}n, the cationic dirhodium complex and bridging chloro ligands form a one‐dimensional zigzag chain, Rh2(acam)4(μ‐Cl)] (Hacam is acetamide). There is a large difference between the two Rh—Cl distances 2.6076 (14) and 2.5027 (14) Å]. Neighboring chains are connected by two N—H⋯O hydrogen bonds per link between the amidate ligands.
Keywords:
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号