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A chloro‐bridged dinuclear phosphinitopalladium complex,di‐μ‐chloro‐bis­[(diphenoxy­phosphinite‐κP)(diphenoxy­phosphinito‐κP)palladium(II)]
Authors:Anna M Trzeciak  Iweta Pryjomska‐Ray  Andrzej Gniewek  Jzef J Zi&#x;kowski  Tadeusz Lis
Abstract:The title compound, Pd2(C12H10O3P)2Cl2(C12H11O3P)2], consists of a dinuclear μ‐chloro‐bridged palladium unit with two diphenoxy­phosphinite groups per Pd atom, linked together by a hydrogen bond. The asymmetric unit contains one half of the mol­ecule, with the other half generated by an inversion centre. The geometry around the P atoms may be described as distorted tetra­hedral. Adjacent mol­ecules of the complex are linked by weak C—H⋯O and C—H⋯Cl hydrogen bonds. The structure is additionally stabilized by π–π stacking inter­actions between the aryl rings. These inter­actions form a herring‐bone pattern in the crystal structure.
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