A chloro‐bridged dinuclear phosphinitopalladium complex,di‐μ‐chloro‐bis[(diphenoxyphosphinite‐κP)(diphenoxyphosphinito‐κP)palladium(II)] |
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Authors: | Anna M Trzeciak Iweta Pryjomska‐Ray Andrzej Gniewek Jzef J Zikowski Tadeusz Lis |
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Abstract: | The title compound, Pd2(C12H10O3P)2Cl2(C12H11O3P)2], consists of a dinuclear μ‐chloro‐bridged palladium unit with two diphenoxyphosphinite groups per Pd atom, linked together by a hydrogen bond. The asymmetric unit contains one half of the molecule, with the other half generated by an inversion centre. The geometry around the P atoms may be described as distorted tetrahedral. Adjacent molecules of the complex are linked by weak C—H⋯O and C—H⋯Cl hydrogen bonds. The structure is additionally stabilized by π–π stacking interactions between the aryl rings. These interactions form a herring‐bone pattern in the crystal structure. |
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