γ‐Modification of poly[(N,N‐diethyldithiocarbamato)silver(I)] |
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Authors: | Zhan Yu Yan‐Wei Song Qian‐Feng Zhang |
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Abstract: | In the title compound, catena‐polytrisilver(I)‐tri‐μ3‐N,N‐diethyldithiocarbamato‐3′κS:1κS′:2κS;1κS:2κS′:3κS;2κS:3κ2S,S′:1′κS′], Ag3(C5H10NS2)3]n, the trigonally and tetrahedrally coordinated Ag atoms are μ3‐bridged by κ3‐ and κ4‐S2CNEt2 ligands to form a ribbon structure along the c axis. There is a twofold axis parallel to the b axis and passing through the tetrahedrally coordinated Ag atom. The S2CNEt2 ligands coordinate the Ag atoms in η1,η2‐ and η2,η2‐fashions, depending on the bridging S atoms. The distances between the trigonal Ag and S atoms are 2.4915 (11)–2.6205 (11) Å, while those between the tetrahedral Ag and S atoms are 2.5457 (11) and 2.7145 (10) Å. The shortest Ag?Ag distance between trigonal Ag atoms is 2.8336 (7) Å, which indicates a weak Ag?Ag interaction, whereas the shortest distance between trigonal and tetrahedral Ag atoms is 3.463 (6) Å, which is considered as non‐bonding. |
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