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Chloro­(μ‐6‐methyl­pyridine‐2‐carboxyl­ato)bis­(6‐methyl­pyridine‐2‐carboxyl­ato)triphenyl­chromium(III)­tin(IV) chloro­triphenyl­tin(IV)
Authors:Guo‐Hai Xu  Jian‐Fang Ma  Ying‐Ying Liu  Shun‐Li Li
Abstract:The title compound, CrSn(C6H5)3(C7H6NO2)3Cl]Sn(C6H5)3Cl(CH4O)], was obtained from the reaction of Ph3SnCl with the complex Cr(C7H6NO2)3] in methanol. The structure contains Ph3SnCl(MeOH)] (A) and Ph3SnClCr(C7H6NO2)3] (B) mol­ecules. In mol­ecule A, the Sn atom of Ph3SnCl is coordinated by one methanol mol­ecule. In mol­ecule B, the Sn atom of Ph3SnCl is coordinated by one carboxyl­ate O atom of Cr(C7H6NO2)3]. Mol­ecules A and B are connected through an O—H⋯O hydrogen bond between a carboxyl­ate O atom and the methanol OH group. Weak C—H⋯Cl inter­actions and O—H⋯O hydrogen bonds extend the components of (I) into a two‐dimensional network.
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