Abstract: | The title compound, CrSn(C6H5)3(C7H6NO2)3Cl]Sn(C6H5)3Cl(CH4O)], was obtained from the reaction of Ph3SnCl with the complex Cr(C7H6NO2)3] in methanol. The structure contains Ph3SnCl(MeOH)] (A) and Ph3SnClCr(C7H6NO2)3] (B) molecules. In molecule A, the Sn atom of Ph3SnCl is coordinated by one methanol molecule. In molecule B, the Sn atom of Ph3SnCl is coordinated by one carboxylate O atom of Cr(C7H6NO2)3]. Molecules A and B are connected through an O—H⋯O hydrogen bond between a carboxylate O atom and the methanol OH group. Weak C—H⋯Cl interactions and O—H⋯O hydrogen bonds extend the components of (I) into a two‐dimensional network. |