(6,7‐Dimethyl‐2,3‐di‐2‐pyridylquinoxaline)bis(3‐methylpyridine)platinum(II) bis(hexafluorophosphate) acetone solvate 0.5‐hydrate |
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Authors: | Archimede Rotondo |
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Abstract: | The crystal structure of the title compound, [Pt(C6H7N)2(C20H16N4)](PF6)2·C3H6O·0.5H2O, is composed of a bivalent square‐planar platinum(II) complex, two PF6− counter‐ions and solvent molecules. The di‐2‐pyridylquinoxaline ligands are known to confer an `L shape' on square‐planar platinum(II) complexes, which also display intercalating properties. The structural characterization reported here is a contribution to a wide‐ranging study focused on structural and dynamical analyses of these substrates, which may provide better insight into their biological mechanisms and activities. The expected `L‐shaped' skeleton of the metallic complex combined with the antiparallel orientation of substituted pyridines (anti conformation) generates chiral objects, found in the solid state as a racemic mixture. |
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