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catena‐Poly[[[triaqua­cobalt(II)]‐μ‐2,6‐dioxo‐1,2,3,6‐tetra­hydro­pyrimidine‐4‐carboxyl­ato(2–)] 1.72‐hydrate]
Authors:Onur ahin  Orhan Büyükgüngr  Dursun Ali Kse  Birgül Zümreoglu‐Karan  Hacali Necefoglu
Abstract:The CoII ion in the title complex {Co(C5H2N2O4)(H2O)3]·1.72H2O}n, has a distorted octa­hedral coordination geometry comprised of three water ligands, one deprotonated pyrimidine N atom and an adjacent carboxyl­ate O atom of one orotate ligand. The sixth coordination site is occupied by an exocyclic O atom from a neighbouring orotate moiety, and through this inter­action a helicoidal chain is formed. The mol­ecules are linked by intra­molecular Owater—H⋯O and inter­molecular N—H⋯O and Owater—H⋯O hydrogen bonds, forming a three‐dimensional network.
Keywords:
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