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MoCu3TeO7Cl2·0.5H2O
Authors:Rie Takagi  Fabienne Duc  Mats Johnsson
Abstract:Single crystals of molybdenum(VI) tricopper(II) tellurium(IV) hepta­oxide dichloride hemihydrate, MoCu3TeO7Cl2·0.5H2O, were synthesized via a transport reaction in sealed evacuated silica tubes. All atoms occupy general positions within the triclinic () unit cell. The building units are irregular CuO4Cl and CuO3Cl2 square pyramids, distorted TeO3+1E trigonal bipyramids (E is the lone pair of TeIV) and irregular MoO5 pyramids. The TeO3+1E, CuO4Cl and CuO3Cl2 polyhedra form (110) layers bridged by Mo atoms. The water mol­ecules are located in [100] channels.
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