Bis(3‐aminopyridine‐κN)(4,4′‐dimethyl‐2,2′‐bipyridine‐κ2N,N′)(perchlorato‐κO)copper(II) perchlorate |
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Authors: | Hui‐Fen Qian Wei Huang |
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Abstract: | The title compound, Cu(ClO4)(C5H6N2)2(C12H12N2)]ClO4, was prepared by in situ partial ligand substitution between 3‐aminopyridine and 4,4′‐dimethyl‐2,2′‐bipyridine at room temperature. The central copper(II) ion is five‐coordinated by one bidentate 4,4′‐dimethyl‐2,2′‐bipyridine molecule, two monodentate pyridine‐coordinated 3‐aminopyridine molecules and one apical O atom from the perchlorate counter‐ion. Intermolecular N—H⋯O and C—H⋯O hydrogen‐bonding interactions form a hydrogen‐bond‐sustained network. |
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