Mechanism of the liquid-phase oxidation of diethyl sulfide catalyzed by heteropoly acids期刊界 All Journals 搜尽天下杂志传播学术成果专业期刊搜索期刊信息化学术搜索

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Mechanism of the liquid-phase oxidation of diethyl sulfide catalyzed by heteropoly acids

Authors:	V E Tarabanko V N Sidelnikov and I V Kozhevnikov

Institution:	(1) Institute of Catalysis, Novosibirsk, USSR

Abstract:	It has been established that in the oxidation of diethyl sulfide by¹⁸O₂ in CH₃C¹⁶O₂H–H₂ ¹⁶O solution at 369 K catalyzed by heteropoly acids, sulfoxide and sulfone with 44–54%¹⁸O enrichment are formed. The process is accompanied by isotope exchange of molecular oxygen. , ¹⁸O₂ CH₃C¹⁶O₂H–H₂ ¹⁶O 369 ¹⁸O 44–54%, .

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