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Ammonium Chloride Promoted Palladium-Catalyzed UIImann Coupling of Aryl Bromide
作者姓名:李金恒  梁云  刘文杰  唐石  谢叶香
作者单位:KeyLaboratoryofChemicalBiology&TraditionalChineseMedicineResearch,CollegeofChemistryandChemicalEngineering,HunanNormalUniversity;Changsha,Hunan410081,China
摘    要:In water, ammonium chloride was found to promote palladium-catalyzed Ullmann coupling reactions of aryl bromides. In the presence of Pd/C, zinc, NH4Cl, and water, coupling of various aryl bromides was carried out smoothly to afford the corresponding homocoupling products in moderate yields.

关 键 词:氯化铵  钯催化剂  芳基溴  UIImann耦合反应  Pd/C

Ammonium chloride promoted palladium‐catalyzed Ullmann coupling of aryl bromide
Jin‐Heng Li,Yun Liang,Wen‐Jie Liu,Shi Tang,Ye‐Xiang Xie.Ammonium Chloride Promoted Palladium-Catalyzed UIImann Coupling of Aryl Bromide[J].Chinese Journal of Chemistry,2004,22(12):1432-1435.
Authors:Jin‐Heng Li  Yun Liang  Wen‐Jie Liu  Shi Tang  Ye‐Xiang Xie
Abstract:In water, ammonium chloride was found to promote palladium‐catalyzed Ullmann coupling reactions of aryl bromides. In the presence of Pd/C, zinc, NH4Cl, and water, coupling of various aryl bromides was carried out smoothly to afford the corresponding homocoupling products in moderate yields.
Keywords:Pd/C  Ullmann coupling reaction  ammonium chloride  aryl bromides
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