Chain transfer mechanism and kinetics in radical telomerization of ethylene with bromalkanes |
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| Authors: | A G Shostenko V E Myshkin and V Kim |
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| Institution: | (1) Mendeleev Institute of Chemical Technology, Moscow, USSR |
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| Abstract: | Rate constants for chain transfer via bromoalkanes of various structure are estimated for primary, secondary and tertiary alkyl radicals and isokinetic dependences are shown to exist for their activation parameters. Isokinetic temperatures are calculated.
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