| 锌与邻菲咯啉和α-萘乙酸配合物的合成、结构和抗菌活性 |
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| 引用本文： | 唐定兴,冯丽霞,张小全.锌与邻菲咯啉和α-萘乙酸配合物的合成、结构和抗菌活性[J].无机化学学报,2006,22(10):1891-1894. |
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| 作者姓名： | 唐定兴 冯丽霞 张小全 |
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| 作者单位： | 安徽工程科技学院生物化学工程系,芜湖,241000 |
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| 摘 要： | The complex with the molecular formula of Zn(Phen)(NAA)2 was synthesized by the reaction of ZnSO4, naphthylacetic acid and phenanthroline in ethanol-water solution at about pH≈7. It was characterized by elemental analysis, IR spectrum and X-ray single crystal diffraction. The antibacterial activity on E. Coli, S. Aureus and B. Subtilis were also been studied. The crystal of the complex belongs to triclinic system with space group P1, a=1.300 2 nm, b=1.306 4 nm, c=1.714 4 nm, α=89.41°, β=77.06°, γ=86.70°, V=2.833 5(2) nm3, Z=4, Dc=1.444 g·cm-3, Mr=615.96, μ(Mo Kα)=0.912 mm-1, the final R=0.039 8 and wR=0.103 4 I>2σ(I)], F(000)=1 272. An asymmetry unit is composed of two independent molecules of Zn(Phen)(NAA)2 with different bond length and bond angles. There exist two kinds of face to face π-π stacking interactions . The complex has a good effect against E. Coli. CCDC: 619222.
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| 关 键 词： | 锌配合物 邻菲咯啉 α-萘乙酸 晶体结构 抗菌活性 |
| 文章编号： | 1001-4861(2006)10-1891-04 |
| 收稿时间： | 2006-04-27 |
| 修稿时间： | 2006-08-11 |
Synthesis, Structure and Antibacterial Activity of the Complex of Zinc with Phenanthroline and Naphthylacetate |
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| TANG Ding-Xing,FENG Li-Xia and ZHANG Xiao-Quan.Synthesis, Structure and Antibacterial Activity of the Complex of Zinc with Phenanthroline and Naphthylacetate[J].Chinese Journal of Inorganic Chemistry,2006,22(10):1891-1894. |
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| Authors: | TANG Ding-Xing FENG Li-Xia and ZHANG Xiao-Quan |
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| Institution: | Department of Biochemical Engineering, Anhui University of Technology and Science, Wuhu, Anhui 241000,Department of Biochemical Engineering, Anhui University of Technology and Science, Wuhu, Anhui 241000 and Department of Biochemical Engineering, Anhui University of Technology and Science, Wuhu, Anhui 241000 |
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