Copper-catalyzed Ullmann-type synthesis of diaryl ethers assisted by salicylaldimine ligands |
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Authors: | Cun-Wei Qian Wen-Lin Lv Qian-Shou Zong Mao-Yuan Wang Dong Fang |
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Institution: | a School of Chemistry and Chemical Engineering, Yancheng Teachers University, Yancheng 224051, China;
b School of Biological and Chemical Engineering, Jiaxing University, Jiaxing 314001, China |
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Abstract: | A series of salicylaldimine ligands were designed to promote the copper-catalyzed Ullmann crosscoupling reaction. After a screening process, 2-((2-isopropylphenylimino)methyl)phenol was found to serve as a good supporting ligand for this reaction. Employing this Schiff-base ligand as a new supporting ligand, the copper-catalyzed coupling reactions of aryl bromides and aryl iodides with various phenols successfully proceeded in good yields under mild conditions. Various diaryl ethers were obtained with excellent yields in dioxane in the presence of K3PO4 and a catalytic amount of copper(I) salt. |
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Keywords: | Copper catalyst Salicylaldimine ligands Ullmann coupling Diaryl ethers |
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