| Synthesis and Crystal Structure of （Z）-Methyl-3-methoxy-2-{2-[（4-（E-3-p-tolylacryloyl）phenoxy）methyl]phenyl}acrylate |
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| 作者姓名： | ZHOU Zhong-Zhen YOU Wen-Wei ZHAO Pei-Liang |
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| 作者单位： | Department of Chemistry, College of Pharmaceutical Sciences, Southern Medical University, Guangzhou 510515, China |
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| 基金项目： | The project was supported by the Science Foundation of the Southern Medical University for New Excellent Talents （No. B 1000374） |
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| 摘 要： | The title compound,(Z)-methyl-3-methoxy-2-{2-(4-(E-3-p-tolylacryloyl)phenoxy)-methyl]phenyl}acrylate,was synthesized and determined by X-ray single-crystal diffraction. The crystal belongs to the triclinic system,space group P1 with a = 8.0157(8),b = 12.5748(13),c = 13.3768(14) ,α = 64.770(2),β = 75.720 (2),γ = 89.784(2)°,μ = 0.085 mm-1,Mr = 442.49,V = 1174.1(2) 3,Z = 2,Dc = 1.252 g/cm3,F(000) = 468,T = 294(2) K,R = 0.0603 and wR = 0.1498 for 2644 observed reflections with I 2σ(I). X-ray diffraction analysis reveals that the single crystal contains strong non-classical hydrogen bonds. The preliminary bioassay showed that the title compound exhibits inhibitory activity against the Pseudoperoniospora cubensis and Rhizoctonia solani at the test concentration of 200 mg/L.
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| 关 键 词： | 晶体结构 丙烯酸酯 甲氧基 苯氧基 合成 苯基 p型 标题化合物 |
Synthesis and Crystal Structure of (Z)-Methyl-3-methoxy-2-{2-[(4-(E-3-p-tolylacryloyl)phenoxy)methyl]phenyl} acrylate |
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| ZHOU,Zhong-Zhen YOU,Wen-Wei ZHAO,Pei-Liang.Synthesis and Crystal Structure of (Z)-Methyl-3-methoxy-2-{2-[(4-(E-3-p-tolylacryloyl)phenoxy)methyl]phenyl} acrylate[J].Chinese Journal of Structural Chemistry,2010,29(10):1574-1578. |
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| Authors: | ZHOU Zhong-Zhen YOU Wen-Wei ZHAO Pei-Liang |
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| Abstract: | The title compound, (Z)-methyl-3-methoxy-2-{2-(4-(E-3-p-tolylacryloyl)phenoxy)-methyl]phenyl}acrylate, was synthesized and determined by X-ray single-crystal diffraction. The crystal belongs to the triclinie system, space group Pi with a = 8.0157(8), b = 12.5748(13), c =13.3768(14)(A),α = 64.770(2),β= 75.720 (2),γ= 89.784(2)°,μ =0.085 mm-1, Mr= 442.49, V =1174.1(2)(A)3,Z = 2,Dc = 1.252g/cm3, F(000)= 468, T= 294(2)K, R = 0.0603 and wR= 0.1498 for 2644 observed reflections with I>2σ(I).X-ray diffraction analysis reveals that the single crystal contains strong non-classical hydrogen bonds. The preliminary bioassay showed that the title compound exhibits inhibitory activity against the Pseudoperoniospora cubensis and Rhizoctonia solani at the test concentration of 200 mg/L. |
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| Keywords: | synthesis crystal structure (Z)-methyl-3-methoxy-2-{2-[(4-(E-3-p-tolylacryloyl)phenoxy)methyl]phenyl}acrylate |
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