Intensities and half-widths at different temperatures for the 201III←000 band of CO2 at 4854 cm−1 |
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Authors: | Francisco PJ Valero Carlos B Suarez Robert W Boese |
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Institution: | Ames Research Center, NASA, Moffett Field, CA 94035, U.S.A. |
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Abstract: | Measurements made at temperatures of 197, 233, and 294°K of the absolute intensities and self-broadening coefficients for the vibration-rotation lines of the 201III←000 band of the 12C16O2 molecule, are reported. From these measurements, values have been derived for the vibration-rotation interaction factor (FVR), the purely vibrational transition moment (|R(O)|), and the intensity (SBand). The results are: EVR(m) = 1+(2.2±0.7)×10?3m+(5.6±1.6)×10×5m2, |R(0)| = (2.064±0.017)×10?3 debye, SBand = 21,329±69 cm?1km?1atm?1STP. The results for the self-broadening coefficients are presented in the text. |
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