A synthesis of the Brewer-Engel and Samsonov-Pryadko-Pryadko electron correlations for metals |
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Authors: | Louis M. Pecora Peter Ficalora |
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Affiliation: | Naval Research Laboratories, Code 6411, Washington, D.C. 20390 USA;Department of Chemical Engineering and Materials Science, Syracuse University, Syracuse, New York 13210 USA |
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Abstract: | A synthesis of the Brewer-Engel and Samsonov-Pryadko-Pryadko electron correlations for metals is presented. Difficulties with both correlations are cleared up. In particular, abandonment of the Brewer-Engel association of sp2 ? fcc in favor of a correlation with the number of d electrons eliminates many of the contradictions of that correlation. In general, by placing greater emphasis on the d electrons in transition metals correlations with many solid state properties become much more straightforward. |
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