Relativistic Hartree-Fock oscillator strengths for the lowest s→p and p→d transitions in the first few members of the Ag(I) and Au(I) isoelectronic sequences,with allowance for cope polarization |
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Authors: | J Migda?ek WE Baylis |
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Institution: | Physics Department, University of Windsor, Windsor, Ontario, Canada N9B 3P4 |
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Abstract: | Relativistic, single-configuration Hartree-Fock oscillator strengths for the lowest ns2S→np2P and np2P→nd2D transitions in the first few members of the silver (n = 5) and gold (n = 6) isoelectronic sequences have been studied, both with and without allowance for core polarization. Core polarization is included by introducing a polarization potential in the one-electron Hamiltonian and by employing the corresponding correction for the dipole-moment operator in the transition matrix element. The results obtained are compared with available experimental data and the influence of core-polarization effects on oscillator strengths is discussed. |
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