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Addition of halogenoacetic esters to aldehydes and ketones in the presence of Fe(CO)5 |
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| Authors: | A B Terentiev T T Vasilieva N A Kuz'mina O V Chakhovskaya E S Brodsky Yu N Belokon' |
| Institution: | (1) A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 117813 Moscow, Russian Federation |
| Abstract: | The use of complex-forming solvents and variations in the reaction temperature made it possible to prepare α-halogeno β-hydroxy carboxylic esters upon addition of halogenoacetic esters to aldehydes and ketones promoted by iron pentacarbonyl. Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 4, pp. 718–720, April, 2000. |
| Keywords: | Reformatsky reaction iron pentacarbonyl halogenoacetic esters aldehydes ketones addition reaction |
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