Stable (aryl)(phosphino)carbenes: new ligands for transition metals |
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| Authors: | Despagnet Emmanuelle Miqueu Karinne Gornitzka Heinz Dyer Philip W Bourissou Didier Bertrand Guy |
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| Affiliation: | Laboratoire d'Hétérochimie Fondamentale et Appliquée (UMR CNRS 5069), Université Paul Sabatier, 118 route de Narbonne, F-31062 Toulouse Cedex 04, France. |
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| Abstract: | The first direct complexation of a stable phosphino carbene to a transition metal center is described. Both eta1- and eta2-coordination modes have been characterized spectroscopically. The Fischer-type structure of the eta1-carbene rhodium complex was revealed by an X-ray diffraction study. |
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