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Sulfated tungstate a heterogeneous acid catalyst for synthesis of 4-aryl-NH-1,2,3-triazoles by 1,3-dipolar cycloaddition of nitroolefins with NaN3
Authors:Snehalata B. Autade
Affiliation:Department of Pharmaceutical Sciences and Technology, Institute of Chemical Technology, Mumbai, MH, India
Abstract:A facile and new method for the synthesis of 4-aryl-NH-1,2,3-triazoles from nitroolefins and NaN3 by 1,3-dipolar cycloaddition reaction, employing a mild solid inorganic acid sulfated tungstate as a heterogeneous catalyst, has been developed. The protocol emphasizes broad substrate scope with many functionalities, less reaction time, stability to open air, easy work-up, and with good to excellent yields.
Keywords:1,3-Dipolar cycloaddition  heterogeneous catalysis  nitrostyrenes  sulfated tungstate  1,2,3-triazoles
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