Titanium(II)-mediated cyclizations of (silyloxy)enynes: a total synthesis of (-)-7-demethylpiericidin A1 |
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| Authors: | Keaton Katie A Phillips Andrew J |
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| Institution: | Department of Chemistry and Biochemistry, University of Colorado, Boulder, 80309-0215, USA. |
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| Abstract: | A concise total synthesis of 7-demethylpiericidin A1 has been completed. The synthesis features a titanium(II)-mediated cyclization of a (silyloxy)enyne as the key step and proceeds in nine steps from tiglic aldehyde. |
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