| Graphene Oxide Doped Poly（hydroxymethylated-3,4- ethylenedioxythiophene）： Enhanced Sensitivity for Electrochemical Determination of Rutin and Ascorbic Acid |
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| 引用本文： | 卢丽敏,徐景坤. Graphene Oxide Doped Poly（hydroxymethylated-3,4- ethylenedioxythiophene）： Enhanced Sensitivity for Electrochemical Determination of Rutin and Ascorbic Acid[J]. 高分子科学, 2014, 32(8): 1019-1031. DOI: 10.1007/s10118-014-1484-z |
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| 作者姓名： | 卢丽敏 徐景坤 |
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| 作者单位： | [1]College of Science, Jiangxi Agricultural University, Nanchang 330045, China; [2]Jiangxi Key Laboratory of Organic Chemistry, Jiangxi Science and Technology Normal University, Nanchang 330013, China |
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| 基金项目： | financially supported by the National Natural Science Foundation of China(Nos.50963002,51073074,51272906,51263010 and 51302117);Natural Science Foundation of Jiangxi Province(Nos.2010GZH0041,20122BAB213007);Jiangxi Provincial Department of Education(Nos.GJJ11590,GJJ10678 and GJJ13258);Jiangxi Science&;Technology Normal University Innovation Fund of Postgraduates(YC2013-X25) |
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| 摘 要： | A novel graphene oxide doped poly(hydroxymethylated-3,4-ethylenedioxythiophene)(PEDOT-MeOH/GO) composite film was synthesized and utilized as an efficient electrode material for simultaneous detection of rutin and ascorbic acid(AA). PEDOT-MeOH/GO films were synthesized on glassy carbon electrode(GCE) by a facile one-step electrochemical approach and were characterized by scanning electron microscopy, UV-Vis spectroscopy, FTIR spectra and electrochemical methods. Then the PEDOT-MeOH/GO/GCE was applied successfully in the simultaneous detection of rutin and AA. The results showed that the oxidation peak currents of rutin and AA obtained at the PEDOT-MeOH/GO/GCE were much higher than those at the traditional conducting polymer PEDOT/GO/GCE, PEDOT-MeOH/GCE, PEDOT/GCE and bare GCE. Under optimized conditions, the linear ranges for rutin and AA are 20 nmol/L-10 μmol/L and 8 μmol/L-1 mmol/L, respectively. The detection limit is 6 nmol/L for rutin and 2 μmol/L for AA(S/N = 3), which are lower than those of the reported electrochemical sensors.
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| 关 键 词： | 氧化物掺杂 氧化石墨 羟甲基化 抗坏血酸 电化学测定 芦丁 灵敏度 扫描电子显微镜 |
Graphene oxide doped poly(hydroxymethylated-3,4-ethylenedioxythiophene): enhanced sensitivity for electrochemical determination of rutin and ascorbic acid |
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| Li-ping Wu,Long Zhang,Li-min Lu,Xue-min Duan,Jing-kun Xu,Tao Nie. Graphene oxide doped poly(hydroxymethylated-3,4-ethylenedioxythiophene): enhanced sensitivity for electrochemical determination of rutin and ascorbic acid[J]. Chinese Journal of Polymer Science, 2014, 32(8): 1019-1031. DOI: 10.1007/s10118-014-1484-z |
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| Authors: | Li-ping Wu Long Zhang Li-min Lu Xue-min Duan Jing-kun Xu Tao Nie |
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| Affiliation: | 1. College of Science, Jiangxi Agricultural University, Nanchang, 330045, China
2. Jiangxi Key Laboratory of Organic Chemistry, Jiangxi Science and Technology Normal University, Nanchang, 330013, China
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| Abstract: | Conducting polymer Graphene oxide Nanocomposites Simultaneous determination Electrochemical sensor. |
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| Keywords: | Conducting polymer Graphene oxide Nanocomposites Simultaneous determination Electrochemical sensor. |
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