N-Arylation of aliphatic, aromatic and heteroaromatic amines catalyzed by copper bis(2,2,6,6-tetramethyl-3,5-heptanedionate) |
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| Authors: | Nitin S Nandurkar |
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| Institution: | Department of Chemistry, Institute of Chemical Technology, University of Mumbai, N.Parekh marg, Matunga, Mumbai 400019, India |
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| Abstract: | Copper bis(2,2,6,6-tetramethyl-3,5-heptanedionate) was found to be an efficient catalyst for N-arylation of aliphatic, aromatic and heteroaromatic amines with aryl iodides/bromides under mild conditions. The system tolerated a variety of hindered and functionalized amines/aryl halides and the desired N-aryl amines were obtained in good to excellent yields. |
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