Iridium-catalyzed carbonyl allylation by allyl ethers with tin(II) chloride |
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| Authors: | Yoshiro Masuyama Masanori Marukawa |
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| Affiliation: | Department of Chemistry, Faculty of Science and Technology, Sophia University, 7-1 Kioicho, Chiyoda-ku, Tokyo 102-8554, Japan |
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| Abstract: | 3-Alkoxypropenes, namely allyl ethers such as allyl butyl ether, allyl 2-hydroxypropyl ether, and diallyl ether, serve as reagents for the allylation of aldehydes with tin(II) chloride in the presence of a catalytic amount of [IrCl(cod)]2 in THF and H2O at 50 °C to produce the corresponding homoallylic alcohols. |
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