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Polystyrene sulfonic acid catalyzed greener synthesis of hydrazones in aqueous medium using microwaves
Authors:Vivek Polshettiwar
Affiliation:Sustainable Technology Division, National Risk Management Research Laboratory, US Environmental Protection Agency, 26 W. Martin Luther King Dr., MS 443, Cincinnati, OH 45268, USA
Abstract:An environmentally benign aqueous protocol for the synthesis of cyclic, bi-cyclic, and heterocyclic hydrazones using polystyrene sulfonic acid (PSSA) as a catalyst has been developed; the simple reaction proceeds efficiently in water in the absence of any organic solvent under microwave irradiation and involves basic filtration as the product isolation step.
Keywords:Hydrazones   Polystyrene sulfonic acid   Aqueous medium   Microwave irradiation   Green chemistry
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