Studies on radical cyclization of 2,3-epoxy alcohols containing a β-(alkoxy)acrylate moiety using Cp<sub>2</sub>TiCl期刊界 All Journals 搜尽天下杂志传播学术成果专业期刊搜索期刊信息化学术搜索

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Studies on radical cyclization of 2,3-epoxy alcohols containing a β-(alkoxy)acrylate moiety using Cp₂TiCl

Authors:	Tushar Kanti Chakraborty Rajarshi Samanta Krishnan Ravikumar

Institution:	Indian Institute of Chemical Technology, Hyderabad 500 007, India

Abstract:	Radical-mediated opening of chiral 2,3-epoxy alcohols, containing suitably positioned β-(alkoxy)acrylate moieties, using Cp₂TiCl triggered intramolecular cyclization to give tetrahydrofuran and tetrahydropyran moieties.

Keywords:	Epoxy alcohol Tetrahydrofuran Tetrahydropyran Sharpless epoxidation Epoxide opening Ti(III)
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