One-pot carbon-carbon bond formation at the β-position of cyclic ketones: oxidative Michael addition with alkyl malonates |
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| Authors: | Jun-ichi Matsuo Hiroki Kawai |
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| Affiliation: | Division of Pharmaceutical Sciences, Graduate School of Natural Science and Technology, Kanazawa University, Kakuma-machi, Kanazawa 920-1192, Japan |
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| Abstract: | A carbon-carbon bond was formed at the β-position of cyclic ketones in a one-pot manner by oxidation with N-tert-butylbenzenesulfinimidoyl chloride, followed by the reaction of malonic acid esters or potassium cyanide. |
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