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A recyclable Cu/Al-HT catalyst for amination of aryl chlorides
Authors:Pravin R. Likhar  R. Arundhathi  M. Lakshmi Kantam
Affiliation:Inorganic and Physical Chemistry Division, Indian Institute of Chemical Technology, Hyderabad 500 007, India
Abstract:A simple Cu/Al-HT catalyzed amination of aryl chlorides with primary and secondary aromatic amines has been developed. This ligand-free heterogeneous Cu/Al-HT catalyst, in conjunction with base, also efficiently works for the amination of aryl chlorides with cycloalkylamines. This method tolerates a variety of functional groups and does not require an expensive additive.
Keywords:N-Arylation   Amination   Cu/Al-HT   Aryl chlorides
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