Biomimetic oxidation of metribuzin with hydrogen peroxide catalyzed by 5,10,15,20-tetraarylporphyrinatoiron(III) chlorides |
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| Authors: | Shive MS Chauhan Pratibha Kumari |
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| Institution: | Bioorganic Laboratory, Department of Chemistry, University of Delhi, Delhi, India |
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| Abstract: | The biomimetic oxidation of metribuzin, a pre- and post-emergence herbicide with hydrogen peroxide catalyzed by 5,10,15,20-tetraarylporphyrinatoiron(III) chlorides TAPFe(III)Cl], has been studied yielding 6-t-butyl-3-methylthio-1,2,4-triazine-5(4H)-one, 4-amino-6-t-butyl-3,5(2H,4H)-dione and 6-t-butyl-1,2,4-triazin-3,5(2H,4H)-dione under various reaction conditions. |
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| Keywords: | Metribuzin Biomimetic oxidation Metalloporphyrin Hydrogen peroxide Herbicide |
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