Preparation and decarboxylative rearrangement of (Z)-enyne esters |
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| Authors: | Jacqueline CS Woo Margaret M Faul |
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| Institution: | Chemical Process Research and Development, Amgen Inc., One Amgen Center Dr., Thousand Oaks, CA 91320, USA |
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| Abstract: | A method to assemble (Z)-enyne esters via palladium-catalyzed cross coupling reactions of enol tosylates is reported. A base-mediated one-pot decarboxylative rearrangement of the enynes to enones is described. The scope of this process is examined. |
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