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Environmentally benign oxidation reaction of aldehydes to their corresponding carboxylic acids using Pd/C with NaBH4 and KOH |
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| Authors: | Minkyung Lim Gwangil An Hakjune Rhee |
| Institution: | a Department of Chemistry and Applied Chemistry, Hanyang University, Ansan Sa 1-Dong 1271, Kyunggi-Do 426-791, Republic of Korea b Department of Advanced Material Chemistry, Korea University, Jochiwon, Choongnam 339-700, Republic of Korea c Radiopharmaceuticals Laboratory, Korea Institute of Radiological and Medical Sciences, Nowon-Gu, Gongneung-Dong 215-4, Seoul 139-706, Republic of Korea |
| Abstract: | Pd/C catalyst in aqueous methanol with sodium borohydride and potassium hydroxide under the air efficiently oxidized aldehydes to their corresponding carboxylic acids at room temperature. The utilization of room temperature reaction, aqueous methanol solvent, and the open-air conditions make this manipulation very interesting for economic and environmental perspectives. |
| Keywords: | Pd/C Oxidation reaction Aldehydes Carboxylic acids NaBH4 KOH Under the air |
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