New diphosphite ligands for enantioselective asymmetric hydroformylation |
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Authors: | Yaping Zou |
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Institution: | 104 Chemistry Building, Department of Chemistry, The Pennsylvania State University, University Park, PA 16802, USA |
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Abstract: | A series of new diphosphite ligands have been easily prepared from BINOL derivatives; moderate enantioselectivities (up to 80% ee) and excellent regioselectivities (b/l up to 98/2) have been achieved in the Rh-catalyzed asymmetric hydroformylation of vinyl acetate. |
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