A chiral ketone for enantioselective recognition of 1,2-amino alcohols |
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Authors: | Raju Nandhakumar |
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Affiliation: | Department of Chemistry and Division of Nano Sciences, Ewha Womans University, Seoul 120-750, South Korea |
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Abstract: | A novel auxillary chiral ketone has been designed, synthesized, and used to enantioselectively recognize 1,2-amino alcohols. This work proves that the keto group can serve as a chiral recognition center by imine formation supported by resonance assisted hydrogen bonding (RAHB). |
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Keywords: | Chiral ketone Enantioselective recognition 1,2-Amino alcohols Imine bond |
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