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(R)-(+)-[VCD(+)945]-4-Ethyl-4-methyloctane, the simplest chiral saturated hydrocarbon with a quaternary stereogenic center |
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| Authors: | Takuma Fujita Shunsuke Kuwahara Atsufumi Nakahashi John Decatur |
| Institution: | a Institute of Multidisciplinary Research for Advanced Materials, Tohoku University, 2-1-1 Katahira, Aoba, Sendai 980-8577, Japan b Graduate School of Advanced Life Science and Frontier Research Center for Post-genome Science and Technology, Hokkaido University, Kita 21 Nishi 11, Sapporo 001-0021, Japan c Department of Chemistry, Columbia University, 3000 Broadway, MC3114, New York, NY 10027, USA |
| Abstract: | Enantiopure (R)-(+)-VCD(+)945]-4-ethyl-4-methyloctane, the simplest chiral saturated hydrocarbon with a quaternary stereogenic center, was synthesized by the use of MαNP acid method, and its absolute configuration was first unambiguously determined by the 1H NMR anisotropy, X-ray crystallography, and VCD methods. |
| Keywords: | (R)-(+)-[VCD(+)945]-4-Ethyl-4-methyloctane Simplest chiral saturated hydrocarbon 1H NMR anisotropy method X-ray crystallography Vibrational circular dichroism |
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